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Sodium tungsten bronze : ウィキペディア英語版 | Sodium tungsten bronze
Sodium tungsten bronze is a form of insertion compound with the formula Na''x''WO3, where ''x'' is equal to or less than 1. Named due to its metallic lustre, its electrical properties range from semiconducting to metallic depending on the concentration of sodium ions present; it can also exhibit superconductivity. ==History== Prepared in 1823 by the chemist Friedrich Wöhler, sodium tungsten bronze was the first alkali metal bronze to be discovered. They owe some of their properties to the relative stability of the tungsten(V) cation that is formed. A similar family of molybdenum bronzes may have been discovered in 1885 by Alfred Stavenhagen and E. Engels,〔 but they are formed in a very narrow range of temperatures and were not reported again until the 1960s.〔
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